The molal freezing point depression constant for H2O, Kf , is given as 1.86 °C.kg/mole. Thus a1. 00 m aqueous solution freezes at -1.86 °C instead of 0.00°C which is the normal freezing point for water.

What is the relationship between freezing point depression and salt concentration?

Salt molecules block water molecules from packing together when temperature is lowered. It then prevents them from becoming ice. More water molecules leave the solid phase than the ones entering the solid phase. Freezing point depression occurs when the freezing point of the liquid is lowered by addition of solute.

What is the freezing point depression constant of NaCl?

To account for this, an additional experimentally measured parameter i is used in the formula for freezing point depression, ΔTf = i * Kf * m . The measured value of van’t Hoff factor for NaCl is 1.9 .

### Does salt cause freezing point depression?

Salt melts ice and helps keep water from re-freezing by lowering the freezing point of water. This phenomenon is called freezing point depression. Salt only helps if there is a little bit of liquid water available. The salt has to dissolve into its ions in order to work.

What is meant by Cryoscopic constant KF?

In thermodynamics, the cryoscopic constant, Kf, relates molality to freezing point depression (which is a colligative property). It is the ratio of the latter to the former: i is the van ‘t Hoff factor, the number of particles the solute splits into or forms when dissolved. b is the molality of the solution.

Does salt increase freezing point?

Ice in contact with salty water therefore melts, creating more liquid water, which dissolves more salt, thereby causing more ice to melt, and so on. The higher the concentration of dissolved salt, the lower its overall freezing point.

## How do you calculate KF value?

Divide the freezing point depression by the molal concentration so you have: Kf = delta Tf / cm. Insert the values for delta Tf and cm. For instance, if you have a solution with a molality of 0.455 which freezes at 3.17 degrees Celsius, then Kf would equal 3.17 divided by 0.455 or 6.96 degrees Celsius.

What is cryoscopic constant or molar depression constant?

Cryoscopic constant : It is the depression of freezing point of the solvent produced on dissolving one mole of a substance in 1000 g of it. It is also called molal depression constant.

What does KB and KF depend on?

Answer: The value of Kb or Kf depends only on the type of solvent & not solute dissolved in it.